期刊
ORGANIC CHEMISTRY FRONTIERS
卷 1, 期 10, 页码 1201-1204出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4qo00229f
关键词
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资金
- Shanghai Rising-Star Program [14QA1400500]
- National Basic Research Program of China (973 Program) [2012CB720300]
- National Nature Science Foundation of China [21102016, 21274023]
- Shanghai Scientific and Technological Innovation Project [13520711500]
A photoinduced highly efficient C-Si bond cleavage reaction of benzylsilanes under the catalysis of HBr was developed. The in situ generated benzyl radical intermediates were aerobically oxidized into benzoic acids highly chemoselectively. In this transformation, HBr not only acted as the single electron transfer mediator for the initial C-Si bond cleavage, but also efficiently catalyzed the oxidation of benzaldehyde intermediates into benzoic acids.
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