4.2 Article

Facile ultrasensitive monitoring of mercury ions in water by fluorescent ratiometric detection

期刊

CENTRAL EUROPEAN JOURNAL OF CHEMISTRY
卷 11, 期 4, 页码 584-593

出版社

SCIENDO
DOI: 10.2478/s11532-012-0193-0

关键词

Chemosensing polymer composition; Mercury ions; Ratiometric fluorescence detection; 3-hydroxychromones; Minimal permitted concentration (MPC)

资金

  1. State Foundation for Fundamental Research of Ukraine [GP/F44/109]

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Prospects for analytical application of 2,5-diphenyloxazole-substituted 3-hydroxychromone for detection of mercury ions are presented. Sensitivity and selectivity for a number of metal ions both in methanol solution and in the plasticized polymer are outlined. Ultrasensitive and highly selective fluorescent ratiometric response of the polymer film containing the title compound for mercury ions in water media is revealed. Reversibility of ratiometric response to mercury ions and influence of plasticizer's content in the polymer film on the optical feedback are also discussed.

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