期刊
FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING
卷 12, 期 3, 页码 400-408出版社
SPRINGER
DOI: 10.1007/s11705-018-1753-4
关键词
iron; Schiff base-like ligands; magnetism; spin crossover; X-ray structures
The synthesis of new Schiff base-like ligands with asymmetric substituents pattern and their iron complexes with pyridine as axial ligand is described. Two of the ligands and one of the iron(II) complexes were characterized by single crystal X-ray structure analysis. One of the the iron(II) complexes shows spin crossover behavior while the others remain in the high spin state. The influence of the reduced symmetry of the ligand on the properties of the complexes is discussed.
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