期刊
CURRENT OPINION IN CHEMICAL ENGINEERING
卷 1, 期 3, 页码 218-224出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.coche.2012.04.002
关键词
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资金
- U.S. Department of Energy Office of Basic Energy Sciences
- DOE Great Lakes Bioenergy Research Center
- U.S. Department of Energy, Office of Science, Office of Biological and Environmental Research
- National Science Foundation [EEC-0813570]
- National Science Foundation Partnership in International Research and Education (PIRE)
- Defense Advanced Research Projects Agency (DARPA)
- Army Research Lab (ARL) through the Defense Science Office Cooperative Agreement [W911NF-09-2-0010/09-005334 B 01]
- Board of Regents of the University of Wisconsin System
- U.S. Department of Energy
Fractionation of lignocellulosic biomass increases process flexibility and allows for integrated processing of C-5 and C-6 sugars. Recent advances using acidic treatments to deconstruct biomass in combination with organic solvents to create biphasic systems have allowed for increased yields of platform chemicals such as furfural, hydroxymethylfurfural, and levulinic acid. Management of the mineral acids used in pretreatment steps remains a challenge, but proper organic solvent selection, such as 2-sec-butylphenol, allows for complete recovery and recycle of mineral acid. Using solvents with high partition coefficients for extraction of products in biphasic unit operations allows the concentrations of products to be increased and improves the efficiency of downstream processing options, such as distillation or further upgrading reactions. Overall, fractionation of lignocellulosic biomass allows for a flexible, integrated processing approach that we hope will advance biorefining operations, allowing commercial biomass processing to become a reality.
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