期刊
ORGANIC CHEMISTRY FRONTIERS
卷 2, 期 5, 页码 459-463出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5qo00012b
关键词
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资金
- National Science Foundation of China [21202129, 21472146]
- Ministry of Science and Technology of PRC (973 program for young scientists) [2014CB548200]
Intramolecular homolytic aromatic silylation of biphenyl-2-hydrosilanes via silyl radicals has been developed for the synthesis of silafluorenes. Moreover, silaindenes are synthesized via a silyl radical cascade process, assembling internal alkynes with readily available arylhydrosilanes by C-H and Si-H cleavage and C-C and C-Si bond formation in one step. These represent a new simple and efficient approach towards the synthesis of benzosilole derivatives.
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