期刊
ORGANIC CHEMISTRY FRONTIERS
卷 2, 期 8, 页码 942-946出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5qo00124b
关键词
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资金
- National Science Foundation of China [21172131]
- State Key Laboratory of Natural and Biomimetic Drugs of Peking University [K20140208]
An efficient I-2-catalyzed cascade coupling protocol was developed for the synthesis of pyrrolo[1,2-a]-quinoxaline and imidazo[1,5-a]quinoxaline derivatives via sp(3) and sp(2) C-H cross-dehydrogenative coupling. A nontoxic, readily available catalyst, I-2, and an oxidant, DMSO, were used in this metal-free process. The target compounds were obtained in good-to-excellent yields with a broad substrate scope.
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