期刊
ORGANIC CHEMISTRY FRONTIERS
卷 2, 期 11, 页码 1468-1474出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5qo00219b
关键词
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资金
- National Natural Science Foundation of China
- National Basic Research Program of China (973 Program) [2014CB745100, 2015CB856500]
- Tianjin Municipal Science & Technology Commission [14JCZDJC33400]
An unprecedented silver-catalyzed 1,3-dipolar cycloaddition reaction of isocyanides with diazo compounds to afford 1,4-disubstituted 1,2,3-triazoles is reported. This reaction exhibits remarkable features, such as high regioselectivity, mild reaction conditions, easily available substrates with simple operation, and good yields with a broad spectrum of substrates. It constitutes an alternative to the well-known CuAAC click reaction.
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