期刊
ORGANIC CHEMISTRY FRONTIERS
卷 2, 期 9, 页码 1018-1021出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5qo00170f
关键词
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资金
- National Science Foundation
- National Basic Research Program of China [2015CB856500]
- Qian Ren Scholar Program of China
- Synergetic Innovation Center of Chemical Science and Engineering (Tianjin)
Silyl cation-promoted aryl C-F activation can lead to formal C-H activation and the formation of new C(ar)-C(alkyl) bonds. Deuterium-labeling experiments suggest an insertion of a phenyl cation into the C-H bond. From competition experiments, a relation between reaction rate and C-H bond strength could be established. Mechanistic parallels are drawn to the Mascarelli reaction.
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