期刊
MACROHETEROCYCLES
卷 4, 期 3, 页码 186-208出版社
IVANOVO STATE UNIV CHEMICAL TECHNOLOGY
DOI: 10.6060/mhc2011.3.08
关键词
Porphyrin-fullerenes; synthesis; Prato reaction; molecular constructs; application
The review focuses current research in the rapidly developing chemistry of porphyrin-fullerene complexes, and highlights recent advances in the synthesis, properties, and potential applications of this family. An overview of the most popular methods to prepare porphyrin complexes with C-60 fullerene exhibiting various types of linkage is given with the main focus on the Prato reaction and its modifications. The discussion of porphyrin-fullerene complexes will include the structures of noncovalently linked porphyrin-fullerenes along with the covalently linked complexes; the chemistry and design of supramolecular ensembles will be covered rather comprehensively. Finally, the potential applications for porphyrin-fullerene conjugates will be discussed.
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