期刊
JOURNAL OF CO2 UTILIZATION
卷 1, 期 -, 页码 60-68出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.jcou.2013.01.001
关键词
Carbon dioxide; Olefin; Alkyne; Carboxylation; Catalysis
资金
- National Natural Science Foundation of China [21172125]
- Ministry of Science and Technology [2012BAD32B10]
- 111 Project of Ministry of Education of China [B06005]
- Committee of Science and Technology of Tianjin
Carbon dioxide utilization has continued to capture the interest of chemists worldwide due to global warming associated with positive carbon accumulation. As an environmentally friendly C1 feedstock, the reaction of carbon dioxide has been extensively investigated for several decades. On the other hand, acrylic acid is a valuable industrial product that is widely used for various important purposes in industry. From the point view of atom- and process-economical chemistry, the most concise and promising route for acrylic acid derivatives synthesis would be direct carboxylation of olefins or alkynes with carbon dioxide. In this review, we would like to discuss and update the latest advances on synthesis of acrylic acid derivatives from unsaturated hydrocarbons and carbon dioxide. (C) 2013 Elsevier Ltd. All rights reserved.
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