期刊
CHEMELECTROCHEM
卷 2, 期 2, 页码 224-230出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.201402297
关键词
carbon dioxide fixation; carbon storage; electrochemistry; green chemistry; molten chlorides
资金
- National Natural Science Foundation of China [51322402]
- Program for New Century Excellent Talents in University [NCET-2011-0577]
- Ministry of Education of China
- Fundamental Research Funds for the Central Universities [FRF-TP-12-002B]
The capture and electrochemical conversion of CO2 in molten LiCl-Li2CO3 salt is proposed. By using an inert platinum anode and a tungsten cathode, the CO32- could be easily converted into carbon and oxygen gas, as well as O2-. The released O2- was responsible for the further capture of CO2. Also, CO2 could be effectively absorbed in such chloride melts with a low content of oxygen ion dissolved. In addition, the produced carbon displayed good performance as a negative electrode material for Li-ion batteries, suggesting that the process is an environmentally friendly way to convert CO2 into energy-storage materials.
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