4.5 Article

Electrochemical Conversion of CO2 into Negative Electrode Materials for Li-Ion Batteries

期刊

CHEMELECTROCHEM
卷 2, 期 2, 页码 224-230

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.201402297

关键词

carbon dioxide fixation; carbon storage; electrochemistry; green chemistry; molten chlorides

资金

  1. National Natural Science Foundation of China [51322402]
  2. Program for New Century Excellent Talents in University [NCET-2011-0577]
  3. Ministry of Education of China
  4. Fundamental Research Funds for the Central Universities [FRF-TP-12-002B]

向作者/读者索取更多资源

The capture and electrochemical conversion of CO2 in molten LiCl-Li2CO3 salt is proposed. By using an inert platinum anode and a tungsten cathode, the CO32- could be easily converted into carbon and oxygen gas, as well as O2-. The released O2- was responsible for the further capture of CO2. Also, CO2 could be effectively absorbed in such chloride melts with a low content of oxygen ion dissolved. In addition, the produced carbon displayed good performance as a negative electrode material for Li-ion batteries, suggesting that the process is an environmentally friendly way to convert CO2 into energy-storage materials.

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