期刊
CHEMELECTROCHEM
卷 1, 期 3, 页码 559-564出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.201300084
关键词
core-shell structures; electrochemistry; hydrothermal synthesis; nanostructures; supercapacitors
资金
- National Natural Science Foundation [21001046, 51002059]
- 973 Program of China [2011CB933300]
- Program for New Century Excellent Talents of the University in China [NCET-11-0179]
To boost the electrochemical utilization and area-specific capacitance, core-shell CuCo2O4@MnO2 heterostructured nanowire arrays on carbon fabrics are synthesized and utilized as high-performance, binder-free, positive electrodes for electrochemical capacitors. The electrode architecture takes advantage of the synergistic effects contributed from both the porous CuCo2O4 nanowire core and the MnO2 shell layer. The as-prepared electrode has a high cell-specific capacitance of 327 Fg(-1), several times higher than that of CuCo2O4 nanowires (57.8 Fg(-1)), at a current density of 1.25 Ag-1 with excellent rate capability (90% capacitance retention at a current density of 6.25 Ag-1) in aqueous electrolyte. A flexible, all-solid-state symmetrical supercapacitor is fabricated by assembling two CuCo2O4@MnO2 nanowire-based electrodes, a high cell-areaspecific capacitance of 714 mFcm(-2) at 1 mAcm(-2) is achieved, which is much higher than values reported earlier. It delivers a high energy density of 94.3 Whcm(-2) at a power density of 0.4757 mWcm(-2) for a voltage window of 1 V. Highly stable electrochemical performance over 3000 cycles is obtained, even when the device is operated under harsh mechanical conditions. These results suggest that the as-prepared CuCo2O4@MnO2/carbon fabric composite architecture is very promising for next-generation high-performance supercapacitors, and this work opens up a novel design of advanced integrated-array electrode materials for high-performance supercapacitors.
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