4.7 Article

Catalytic dehydrogenative borylation of terminal alkynes by POCOP-supported palladium complexes

期刊

INORGANIC CHEMISTRY FRONTIERS
卷 2, 期 8, 页码 720-724

出版社

CHINESE CHEMICAL SOC
DOI: 10.1039/c5qi00074b

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资金

  1. US National Science Foundation [CHE-1300299]
  2. Welch Foundation [A-1717]
  3. Division Of Chemistry
  4. Direct For Mathematical & Physical Scien [1300299] Funding Source: National Science Foundation

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A (POCOP)-supported palladium complex was used to catalyse the dehydrogenative borylation of terminal alkynes to form alkynylboronates. Competing hydrogenation reactions could be mitigated through the use of additives such as phosphines or elemental mercury.

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