Organic-sulfur-zinc hybrid nanoparticle for optical applications synthesized via polycondensation of trithiol and Zn(OAc)2

Organic-sulfur-zinc hybrid materials were prepared via polycondensation of Zn(OAc)(2) and trithiols bearing various alkyl groups. A soluble nanoparticle could be obtained by the polycondensation using a trithiol bearing octadecyl moieties. The good dispersing ability as nano-scaled particles was confirmed by dynamic light scattering and atomic force microscopy analyses. This hybrid nanoparticle was miscible with poly(methyl methacrylate) and served as a refractive additive to increase refractive indexes. The calculated refractive index value for the nanoparticle was 1.58.