期刊
NANO ENERGY
卷 9, 期 -, 页码 364-372出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.nanoen.2014.08.011
关键词
Iron oxide; Graphene foam; Carbon nanotubes; Electrochemical energy storage; Lithium ion battery
A novel flexible and lightweight Fe2O3-based lithium-ion battery anode has been developed by growing porous alpha-Fe2O3 nanorods onto carbon nanotubes-graphene foam (CNT-GF). The CNT-GF 3D network provides a highly conductive, high surface areas and lightweight scaffold for the active Fe2O3 nanorods. Such unique electrodes for lithium-ion battery exhibit an 80% initial columbic efficiency, high-rate capabilities, and >1000 mA h/g capacities at 200 mA/g up to 300 cycles without obvious fading. These properties can be attributed to the fast electrochemical reaction kinetics and electron transport rendered by the conductive 3D network. Our structural design protocol can be extended to many other nanostructured metal oxides or sulfides, and thus provides a new strategy for construction of high-performance electrodes for energy storage. (C) 2014 Elsevier Ltd. All rights reserved.
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