期刊
NANO ENERGY
卷 10, 期 -, 页码 295-304出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.nanoen.2014.10.004
关键词
Na-ion batteries; FeE3; Cathode; High performance
类别
资金
- 100 Talents Programme of The Chinese Academy of Sciences
- National Program on Key Basic Research Project of China (973 Program) [2012CB215500]
- fundamental research funds for the central universities
- National Natural Science Foundation of China [51372007, 21301014]
A strategy for enabling highly insulated FeF3 as high performance cathode materials for NIBs is proposed and realized, through constructing metallic Fe and reduced graphene oxide (RGO) double enhancement conducting matrix, wherein both the metallic Fe and active FeF3 are in situ electrochemically generated from one FeF2 grain (as precursor of FeF3) to ensure their desired homogenous and intimate contact. The efficacy of this concept is demonstrated by the superior electrochemical performance of the generated FeF3-Fe-RGO composite including high capacity of 150 mA h g(-1) at a current density of 50 mA g(-1), good cycle stability, and high power capability at room temperature, which could be reasonably attributed to homogeneous conductive matrix composed of metallic Fe and RGO in the composite and especially their ideal contact with the active FeF3 component. The strategy is simple yet very effective and also because of its versatility, it may be easily extended to other next generation high-capacity electrode materials while with low electrical conductivity. (C) 2014 Elsevier Ltd. All rights reserved.
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