期刊
NANO ENERGY
卷 2, 期 5, 页码 787-793出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.nanoen.2013.02.001
关键词
Chalcogenides; Reduced graphene oxide; Lithium-ion batteries; Cyclability and rate capability; Percolation
类别
资金
- SSCU
- IISc
- CSIR
- Department of Science and Technology (DST)-Nano Mission
- Ministry of Communication and Information Technology (MCIT, Centre of Excellence in Nanoelectronics, Phase II grant) of Government of India
The aim of the contribution is to introduce a high performance anode alternative to graphite for lithium-ion batteries (LiBs). A simple process was employed to synthesize uniform graphene-like few-layer tungsten sulfide (WS2) supported on reduced graphene oxide (RGO) through a hydrothermal synthesis route. The WS2-RGO (80:20 and 70:30) composites exhibited good enhanced electrochemical performance and excellent rate capability performance when used as anode materials for lithium-ion batteries. The specific capacity of the WS2-RGO composite delivered a capacity of 400-450 mAh g(-1) after 50 cycles when cycled at a current density of 100 mA g(-1). At 4000 mA g(-1), the composites showed a stable capacity of approximately 180-240 mAh g(-1), respectively. The noteworthy electrochemical performance of the composite is not additive, rather it is synergistic in the sense that the electrochemical performance is much superior compared to both WS2 and RGO. As the observed lithiation/delithiation for WS2-RGO is at a voltage 1.0 V (approximate to 0.1 V for graphite, Li* /Li), the lithium-ion battery with WS2-RGO is expected to possess high interface stability, safety and management of electrical energy is expected to be more efficient and economic. (C) 2013 Elsevier Ltd. All rights reserved.
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