期刊
NANO ENERGY
卷 2, 期 2, 页码 257-267出版社
ELSEVIER
DOI: 10.1016/j.nanoen.2012.09.004
关键词
N-doped; alpha-Fe2O3; Graphene; Lithium-ions batteries; Sandwich; Nanoplatelets
类别
资金
- Japan Society for Promotion of Science (JSPS)
- International Center for Young Scientists (ICYS)
- International Center for Materials Nanoarchitectonics (MANA) tenable at the National Institute for Materials Science (NIMS)
Nowadays, 2D nanosheets or nanoplatelets have attracted great attention due to their wide applications. However, the synthesis of 2D alpha-Fe2O3 nanosheets with well-defined hexagonal shape is extremely challenging, because the selective growth along one specific facet is very hard to be realized. In our work, we studied the non-capping ligand mediated reaction within graphene layer chamber, and successfully synthesized alpha-Fe2O3 hexagonal nanoplatelets sandwiched between graphene layers (HP-Fe-G). These materials exhibit an improved electrochemical performance compared with the pre-existing alpha-Fe2O3 nanoparticles loaded graphene (G-Fe2O3) composites because of the uniqueness of such architectures: thin nanoplatelets, large enough sandwiched spaces to buffer the volume expansion and N-doped graphene. HP-Fe-G delivered an ultrahigh reversible capacity of 1100 mAh/g after 50 cycles, thus higher than their theoretical value (926 mAh/g); while G-Fe2O3 composites showed relatively low capacity retention even after only 20 cycles (582 mAh/g). In addition, HP-Fe-G also reveal superior rate capability, 887 mAh/g at 1C; in comparison, this value was only 135 mAh/g at 1C for G-Fe2O3. (C) 2012 Elsevier Ltd. All rights reserved.
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