期刊
JOURNAL OF NATURAL GAS SCIENCE AND ENGINEERING
卷 18, 期 -, 页码 406-411出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.jngse.2014.04.004
关键词
OCM; Natural gas processing; Nanofiber catalyst; Electrospinning; Exothermic reactions; Rare earth oxide catalysts
资金
- NSF IGERT: Materials Creation Training Program (MCTP) [DGE-0654431]
- University of California, Los Angeles (UCLA) Graduate Division Fellowship
The effects of changes in various operating conditions were explored on the performance of an oxidative coupling of methane (OCM) reaction using La2O3-CeO2 nanofiber fabric catalysts in a packed bed reactor. The operating conditions were: 1 atm pressure, CH4/O-2 ratio 4-7, feed flow rate 80-320 sccm, catalyst loading 5-20 mg, feed gas temperature 300-620 degrees C. These studies revealed that the rates of the OCM reaction is largely dominated by mass transfer limitations as evidenced by increases in reactor bed temperatures with increasing feed flow rates. C2+ selectivities and yields of up to 70% and 18% respectively were also attained. Experiments with different catalyst loadings indicated that short catalytic beds are preferred for increasing C2+ selectivities in OCM reactors. (C) 2014 Elsevier B.V. All rights reserved.
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