期刊
JOURNAL OF MATERIALS CHEMISTRY C
卷 2, 期 37, 页码 7952-7959出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4tc00538d
关键词
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资金
- European Union
- Freistaat Thuringen
- Leuchtstoffwerk Breitungen GmbH (Germany) [2008FE0070]
- National Natural Science Foundation of China [11104298, U1332202]
- Innovation Program of Shanghai Institute of Ceramics [Y34ZC130G]
RE3+ (RE = Pr, Sm, and Tb)-doped SrAlSi4N7 samples were synthesized by a solid-state reaction method at high temperature, and their photoluminescence properties were investigated. It is noticeable that the 5d bands of Pr3+ and Tb3+ are at rather low energy in SrAlSi4N7 compared to oxides. Typical 4f(2) -> 4f(2) emission lines (480-800 nm) of Pr3+ under 4f(2) -> 4f(1)5d(1) excitation were observed in Pr3+-doped SrAlSi4N7. Sm3+-doped SrAlSi4N7 shows red emission originating from (4)G(5/2) -> H-6(J) (J = 5/2, 7/2 and 9/2) transitions, and the charge transfer band of Sm3+ was observed at an unusually low energy of 3.98 eV. The Tb3+-doped sample exhibits D-5(3) -> F-7(J) (J = 6, 5, 4, 3, 2, 1) (blue) and D-5(4) -> F-7(J) (J = 6, 5, 4, 3) (green) line emissions in the wavelength range of 375-650 nm under the direct Tb3+ 4f(8) -> 4f(7)5d(1) excitation. The bands at about 256 nm in the excitation spectra are attributed to the host lattice absorption. In addition, there is energy transfer from the host lattice to the luminescent activators (Pr3+, Sm3+, and Tb3+). The energy level diagram containing the position of the 4f and 5d levels of all divalent and trivalent lanthanide ions relative to the valence and conduction band of SrAlSi4N7 has been constructed and discussed.
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