期刊
JOURNAL OF MATERIALS CHEMISTRY B
卷 1, 期 31, 页码 3742-3753出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3tb20193g
关键词
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Hydrogen-bonding (H-bonding) is a relatively strong, highly directional, and specific noncovalent interaction present in many organic molecules, and notably is responsible for supramolecular ordering in biological systems. The H-bonding interactions play a role in many organic electrically conducting materials - in particular in those related to biology, e.g. melanin and indigo. This article aims to highlight recent work on application of nature-inspired H-bonded organic molecules in organic electronic devices. Three topics are covered in this brief review: (1) electrical and ionic conduction in natural H-bonded systems, (2) semiconducting properties of H-bonded organic pigments, and (3) exploitation of H-bonding for supramolecular assembly of organic conductors. H-bonding interactions are ubiquitous in biology, thus making the study of H-bonded organic semiconductors highly pertinent where interfacing of electronics with biological systems is desired.
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