期刊
JOURNAL OF MATERIALS CHEMISTRY B
卷 1, 期 38, 页码 5092-5099出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3tb20676a
关键词
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资金
- DFG [EH 394/1-1]
- CryPhys Concept Program (BMBF)
- Kruger Research School
- Biohydrometallurgical Center for Strategic Elements (BHMZ) at TU Bergakademie Freiberg
- Mobilnosc Plus Programme [920/MOB/2012/0]
- Cluster of Excellence Structure Design of Novel High-Performance Materials via Atomic Design and Defect Engineering (ADDE)
- European Union
- Ministry of Science and Art of Saxony (SMWK).
Chitinous scaffolds isolated from the skeleton of marine sponge Aplysina cauliformis were used as a template for the in vitro formation of zirconium dioxide nanophase from ammonium zirconium(IV) carbonate (AZC) under extreme conditions (150 degrees C). These novel zirconia-chitin based composites were prepared for the first time using hydrothermal synthesis, and were thoroughly characterized using a plethora of analytical methods. The thermostability of the chitinous 3D matrix makes it ideal for use in the hydrothermal synthesis of monoclinic nanostructured zirconium dioxide from precursors like AZC. These zirconium-chitin composites have a high potential for use in a broad range of applications ranging from synthetic catalysis to biocompatible materials for bone and dental repair. The synthetic methods presented in this work show an attractive route for producing monoclinic zirconium dioxide on a 3D biocompatible scaffold with ease.
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