期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 6, 期 37, 页码 17982-17993出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ta06670a
关键词
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资金
- Hunan Province Science and Technology Plan Projects [2017TP1009]
- Hunan Province Natural Science Foundation [2018JJ3042]
- National Natural Science Foundation of China [51502086]
FeCl3-intercalated graphite intercalation compounds (GICs) show fascinating potential as anodes for high-performance lithium ion batteries (LIBs) due to their excellent reaction reversibility, low volume change and high volumetric energy density. Despite the recent success in the application of FeCl3-GICs in LIBs, the issue of dissolution of chlorides and the relevant Li-ion storage mechanism have not been well handled. Herein, we have designed and developed a type of FeCl3-intercalated GIC with abundant epoxy functional groups, which provide a strong chemical anchoring effect for effectively immobilizing chlorides in the interlayer space of graphite layers. By combining the first-principles calculations and experimental studies, it is discovered that the electronic decoupling effect of the adjacent graphite layers due to the intercalation of FeCl3 at a molecular level will significantly promote the amount of Li-ions stored in graphite accompanied by the formation of a stable discharge product of CLi. Benefiting from the strong chemical binding strength and the change of electronic characteristics, reversible capacities up to 1371 mA h g(-1) with a capacity retention of 98% after 50 cycles are attained. Our study provides a new route to restrict the dissolution of chlorides and may open the gate for metal chloride-based materials as high-capacity electrochemical energy storage systems.
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