期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 6, 期 37, 页码 18206-18215出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ta04919j
关键词
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资金
- National Research Foundation of Korea (NRF) - Ministry of Science and ICT (MSIT) of Korea [NRF-2012M3A6A7054861, NRF-2014M3A6A7060583, NRF-2015M1A2A2053004, NRF-2016M3D1A1027663, NRF-2016M3D1A1027664]
- National Research Foundation of Korea [2016M3D1A1027664, 2012M3A6A7054861] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
The effect of perovskite film thickness on the current density (J)-voltage (V) hysteresis is investigated with a normal planar perovskite solar cell (PSC) having the FTO/ETL/MAPbI(3)/spiro-MeOTAD/Au structure (ETL = electron transporting layer, MA = methylammonium, and spiro-MeOTAD = 2,2,7,7-tetrakis-(N,N-di-4-methoxyphenylamino)-9,9-spirobifluorene). A compact TiO2 (c-TiO2) layer is used as an ETL, which is compared with a PCBM ETL and a c-TiO2/PCBM bilayered ETL. The MAPbI(3) layer thickness is varied from 100 nm to 800 nm by controlling the precursor solution concentration. The hysteresis increases with perovskite layer thickness for the c-TiO2 layer, while the hysteresis decreases with increasing the perovskite layer thickness in the presence of PCBM. Deep trap states are much more reduced upon inserting PCBM compared with those of the c-TiO2 case, indicative of fewer traps for non-radiative recombination. The ideality factor obtained from the light-dependent open-circuit voltage (V-oc) increases for the c-TiO2 layer but decreases for both the c-TiO2/PCBM bilayer and the PCBM layer as the perovskite layer thickness increases, which again supports that the dependence of hysteresis on the perovskite thickness is related to trap states, that is, decreases in deep trap states can reduce hysteresis. From the capacitance-frequency studies, it is found that the low-frequency capacitance correlates with the observed hysteresis, where it increases for the c-TiO2 layer but decreases for the PCBM containing ETLs with perovskite thickness. This work provides important insight into the hysteresis behavior of PSCs, where the hysteresis depends not only on the nature of the ETL but also on the degree of recombination in the bulk perovskite.
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