期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 2, 期 14, 页码 4961-4969出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ta14607c
关键词
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资金
- National Natural Science Foundation of China [U1034003]
- Natural Science Foundation of Heilongjiang Province [ZD201002. B201105]
- Science Foundation of Heilongjiang Province for Youth scientists [QC2010122]
- Heilongjiang Provincial Education Department [12511z024]
- Program for Innovative Research (Team) in Harbin
- Heilongjiang University [RC2012XK018005, Hdtd2010-02]
In this paper, highly mesoporous hierarchical nickel and cobalt double hydroxide composites (NCDHs) have been synthesized via a simple reflux method. The synthesized NCDH composites with a mass ratio of 100 : 20 for Ni(NO3)(2)center dot 6H(2)O/Co(NO3)(2)center dot 6H(2)O (NCDH-20) contained a lot of oxygen defect sites, and chemisorbed water connects the adjacent Ni(OH)(2) layers. The porous hierarchical nanostructures provide natural channels for the effective and fast transportation of carriers. Furthermore, the NCDH-20 sensor exhibits excellent gas-sensing properties, such as a low detection limit of 0.97 ppm and short response time of 0.6 s to 97 ppm NOx, due to the layered single crystal structure and unique gallery pathway. The NCDH-20 sensor with ultrafast NOx sensing has significant applications for gas sensing.
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