期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 2, 期 29, 页码 11246-11253出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta01494d
关键词
-
资金
- CSIR, New Delhi
- DST, New Delhi
A ruthenium trinuclear polyazine complex was synthesized and subsequently immobilized through complexation to a graphene oxide support containing phenanthroline ligands (GO-phen). The developed photocatalyst was used for the photocatalytic reduction of CO2 to methanol, using a 20 watt white cold LED flood light, in a dimethyl formamide-water mixture containing triethylamine as a reductive quencher. After 48 h illumination, the yield of methanol was found to be 3977.57 +/- 5.60 mu mol g(cat)(-1). The developed photocatalyst exhibited a higher photocatalytic activity than graphene oxide, which provided a yield of 2201.40 +/- 8.76 mu mol g(cat)(-1). After the reaction, the catalyst was easily recovered and reused for four subsequent runs without a significant loss of catalytic activity and no leaching of the metal/ligand was detected during the reaction.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据