期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 2, 期 42, 页码 17962-17970出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta03604b
关键词
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资金
- MOST [2014CB239702]
- National Science Foundation of China [51302083, 51172071, 51272077]
- Fundamental Research Funds for the Central Universities
- Shanghai Pujiang Program
The intercalation pseudocapacitance which leads to the extraordinary charge storage properties has been confirmed as an intrinsic capacitive property of orthorhombic Nb2O5 (T-Nb2O5) nanocrystals. However, the poor electronic conductivity of T-Nb2O5 nanocrystals may limit their electrochemical utilization and high-rate performance especially for thick electrodes with high mass loadings. To address this issue, we herein reported a hydrothermal-heat treatment method to anchor T-Nb2O5 nanocrystals on conductive graphene sheets, which form a layer-by-layer integrated electrode with much shortened ion transport paths and results in excellent electrochemical capacitive properties, including high capacitance (626 C g(-1)), excellent rate handling and cyclic stability. Furthermore, asymmetric supercapacitors were constructed by using the high-rate response T-Nb2O5/graphene nanocomposite and mesoporous carbon as the negative and positive electrode, respectively. The asymmetric supercapacitor could deliver a high energy density of 16 W h kg(-1) at an unprecedented power density of 45 kW kg(-1) (discharge time of 1.2 s). The outstanding power properties of the supercapacitors are mainly attributed to the improved high-rate Li-insertion/extraction capability of the T-Nb2O5/graphene electrode and appropriate pairing of the mesoporous carbon electrode.
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