期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 2, 期 30, 页码 11753-11758出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta01269k
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-
资金
- MOE, Singapore Ministry of Education [MOE2012-T2-2-102]
A soft-templating hydrothermal approach is developed for synthesizing nitrogen (N)-doped mesoporous carbon. D- Fructose and dicyandiamide (DCDA) are used as the starting materials for carbon and nitrogen precursors, respectively, and Pluronic F127 as the soft template. N-doped mes,oporous carbon shows a significant improvement in electrical conductivity and specific capacitance (212 F g(-1) under 1 mV s(-1) scan rate), compared with the un-doped carbon derived from the same process. A tunable N-doping level (from 4.5 to 14.5 wt%) and specific surface area (ranging from 375 to 730 m(2) g(-1)) are realized by changing the DCDA to b-Fructose weight ratio. The three factors that affect the electrochemical performance, including the specific surface area, electrical conductivity and pseudocapacitance, have been systematically studied. Doping of 6.0 wt% N into carbon appears to be the optimum level for obtaining high electrochemical capacitance. In this work, the effects of N-doping and the interactions among the three factors affecting the capacitance are clarified, shedding light on the future work on the rational design of electrode materials for improved electrochemical performance.
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