4.6 Article

Alumina-supported cobalt-adeninate MOF membranes for CO2/CH4 separation

期刊

JOURNAL OF MATERIALS CHEMISTRY A
卷 2, 期 5, 页码 1239-1241

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ta14058j

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资金

  1. NSF CAREER award (CBET) [1054 150]
  2. National Energy Technology Laboratory's Regional University Alliance (NETL-RUA), a collaborative initiative of the NETL [DE-FE0004000]
  3. Directorate For Engineering
  4. Div Of Chem, Bioeng, Env, & Transp Sys [1054150] Funding Source: National Science Foundation
  5. Div Of Chem, Bioeng, Env, & Transp Sys
  6. Directorate For Engineering [1449852] Funding Source: National Science Foundation

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The synthesis of continuous cobalt-adeninate MOF (bio-MOF-13 (I) and bio-MOF-14 (II)) membranes supported on porous alumina tubes is demonstrated. The membranes showed high CO2 permeabilities and low to moderate CO2 separation selectivities for CO2/CH4 gas mixtures. The observed CO2/CH4 selectivities are attributed to preferential CO2 adsorption within the framework.

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