4.6 Article

Nitrogen-doped open pore channeled graphene facilitating electrochemical performance of TiO2 nanoparticles as an anode material for sodium ion batteries

期刊

JOURNAL OF MATERIALS CHEMISTRY A
卷 2, 期 15, 页码 5182-5186

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta00041b

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资金

  1. Secondary Battery Program [2010-0029042]
  2. National Research Foundation [2012-0001174]
  3. Priority Research Centers Program [2011-0031407]
  4. Global Frontier R&D Program on Center for Hybrid Interface Materials (HIM) [2013-073298]
  5. Ministry of Science, ICT & Future Planning
  6. National Research Foundation of Korea (NRF)
  7. Ministry of Science, ICT & Future Planning [2011-0028737]
  8. Korea Center for Artificial Photosynthesis (KCAP) located in Sogang University [2009-0093881]

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We report that titanium dioxide nanoparticles anchored on nitrogen-doped open pore channeled graphene exhibit high performance as anode materials for sodium ion batteries with a high reversible capacity of 405 mA h g(-1) at a current density of 50 mA g(-1), excellent cycle stability with a capacity of 250 mA h g(-1) over 100 charge-discharge cycles at a current density of 100 mA g(-1), and superior rate capability. Also, it shows that high electrochemical performance is attributed to the facilitated ion diffusion by their open pore channels, in addition to the promoted electron transfer in electrochemical reactions by nitrogen-doping.

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