期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 2, 期 43, 页码 18360-18366出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta02734e
关键词
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资金
- NNSFC [21173021, 21231002, 21276026, 21471016, 21271023]
- 111 Project [B07012]
- 973 Program [2014CB932103]
- Institute of Chemical Materials, China Academy of Engineering Physics [20121941006]
In this work, we report an N-doped porous carbon monolith used for the first time as a catalyst for the cycloaddition of CO2 to cyclic carbonates. It acts as an efficient, single-component, metal-, solvent-and halogen-free catalyst for the formation of chloropropene carbonate from CO2 and epichlorohydrin. The N-doped carbon monolith AA-950 significantly exhibited a high CO2 capture capacity of 16.20 mmol g(-1) (298 K and 20 bar) and high conversion of epoxides. A catalytic mechanism has also been proposed based on the basis of DFT calculations. Our findings may trigger interest in the studies of carbon materials for CO2 capture and conversion performance.
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