4.6 Article

Long cycling life of Li2MnSiO4 lithium battery cathodes under the double protection from carbon coating and graphene network

期刊

JOURNAL OF MATERIALS CHEMISTRY A
卷 1, 期 12, 页码 3856-3859

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ta01521a

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资金

  1. National Key Project on Basic Research [2011CB935904]
  2. National Natural Science Foundation of China [21171163, 91127020]

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Li2MnSiO4 possesses a high theoretical capacity of 332 mA h g(-1) as a lithium battery cathode, but it suffered from rapid capacity fading due to the structural instability and manganese dissolution during cycles. Herein, we developed a unique reduced graphene oxide (RGO)@Li2MnSiO4@C composite as a cathode material for lithium ion batteries. Under the double protection from RGO and carbon coating, Li2MnSiO4 demonstrated outstanding electrochemical performance with a high capacity of 290 mA h g(-1) at 0.05 C, and a long cycling life up to 700 cycles at 1 C.

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