期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 1, 期 37, 页码 11145-11151出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ta11949a
关键词
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资金
- National Natural Science Foundation of China [51202004, 21173120]
- Nature Science Foundation of Anhui Province [KJ2013A051]
- Specialized Research Fund for the Doctoral Program of Higher Education of China [20060287026]
- Nature Science Foundation of Jiangsu Province [BK2011030]
- Foundation of Key Laboratory of Colloid and Interface Chemistry (Shandong University), Ministry of Education [201201]
We have developed a facile yet scalable polymer-assisted chemical solution route to prepare a three-dimensional (3D) hierarchical porous network-like NiCo2O4 framework for advanced electrochemical capacitors (ECs). The unique interconnected hierarchical porous framework is constructed by nanosized spinel NiCo2O4 building blocks of 20-30 nm size, thus, a 3D continuous electron transport expressway, convenient electrolyte penetration-diffusion and large electrode-electrolyte interface are obtained simultaneously. The combination of these appealing structural features in the striking network-like NiCo2O4 framework results in a drastically enhanced kinetic behavior, large specific capacitance (SC) and a remarkable cycling stability at high rates. The unique network-like NiCo2O4 electrode features a SC of 587 F g(-1) at 2 A g(-1), and can deliver up to 518 F g(-1) at a large current density of 16 A g(-1). Also, a SC deterioration of similar to 6% of the maximum SC is evident after continuous 3500 charge-discharge cycles at varying current densities, ranging from 2 to 16 A g(-1). Furthermore, the synthetic strategy presented here can be easily extended to fabricate other binary complex metal oxides and/or ternary metal oxides with a controlled composition and porous structure, which may be promising candidates for high-performance ECs, and even advanced Li-ion batteries.
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