期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 1, 期 28, 页码 8280-8286出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ta11098b
关键词
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资金
- Natural Science Foundation of China [50978132, 51178213, 51238002, 51272099, 51008149, 51266011]
- Program for New Century Excellent Talents in University [NCET-11-1004]
- Cultivating Program for Young Scientists of Jiangxi Province of China [20112BCB23016]
- National High Technology Research and Development Program of China [2009AA062905, 2011AA060604]
- Natural Science Foundation of Jiangxi Province [20122BAB213014, 20114BAB203018]
- Department of Education Fund of Jiangxi Province [GJJ13506, GJJ11508]
A novel Pb(II) ion-imprinted crown ether (Pb(II)-IIP) was prepared by inverse emulsion polymerization using 4-vinylbenzo-18-crown-6 as a functional monomer. Pb(II)-IIP showed higher capacity and selectivity than the non-imprinted crown ether (NIP). The monolayer adsorption capacities of Pb(II)-IIP and NIP for Pb(II) ions were 27.95 and 13.54 mg g(-1), respectively. The relative selectivity coefficients of Pb(II)-IIP for Pb(II)/Zn(II), Pb(II)/Co(II), Pb(II)/Ni(II) and Pb(II)/Cd(II) were 617.79, 500.56, 52.28 and 201.15, respectively. Kinetics studies showed that the adsorption process closely agreed with a pseudo-second-order model. Pb(II)-IIP exhibited good regeneration, and the adsorption capacity of Pb(II)-IIP was stable within the first three cycles without obvious decrease. Moreover, Pb(II)-IIP showed almost 100% removal efficiency for Pb(II) ions in real environmental water samples, indicating that Pb(II)-IIP could have wide application prospects in Pb(II) removal.
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