期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 1, 期 33, 页码 9422-9426出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ta10956a
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资金
- National Natural Science Foundation of China [21273197, U1162201]
- State Basic Research Project of China [2009CB623501]
- National High-Tech Research and Development Program of China [2013AA065301]
- Fundamental Research Funds for the Central Universities [2013XZZX001]
Sulfonated hollow sphere carbon (HSC-SO3H) was synthesized from carbonization of a SiO2-polymer core-shell structure, followed by removal of the SiO2 core and sulfonation with chlorosulfonic acid. HSC-SO3H shows superior performances in acetalisation of glycerol, which is related to the hollow sphere carbon shell with rich microporosity for good mass transfer in the reaction.
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