4.6 Article

Composite cathodes composed of NdBa0.5Sr0.5Co2O5+delta and Ce0.9Gd0.1O1.95 for intermediate-temperature solid oxide fuel cells

期刊

JOURNAL OF MATERIALS CHEMISTRY A
卷 1, 期 3, 页码 515-519

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ta00025c

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资金

  1. WCU (World Class University) program [R31-2009-000-20012-0]
  2. Basic Research Program [2012-R1A1A1013380]
  3. National Research Foundation of Korea [2011-0010773]
  4. Ministry of Education, Science and Technology
  5. New & Renewable Energy of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) [20113020030060]
  6. Korea government Ministry of Knowledge Economy

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The electrochemical properties of a composite cathode composed of NdBa0.5Sr0.5Co2O5+delta (NBSCO) and Ce0.9Gd0.1O1.95 (GDC) are investigated for intermediate-temperature solid oxide fuel cells (IT-SOFCs). In particular, cells based on NBSCO-GDC composite cathodes demonstrated higher performance than those based on a NBSCO cathode, probably due to the extended triple phase boundary (TPB) length. The oxygen reduction mechanism on the NBSCO-GDC composite cathodes is proposed to explain the superior electrochemical behaviour.

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