期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 1, 期 42, 页码 13357-13362出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ta12326j
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资金
- Australian Research Council
The synthesis, structure, magnetic and electric conductivity properties of Mg doped SrIrO3 are described. Doping SrIrO3 with Mg favours an orthorhombic structure over the hexagonal face-sharing structure. Polycrystalline samples of the type SrIr1-xMgxO3 with an orthorhombic perovskite-type structure have been formed for 0.2 < x < 0.33. At x 0.2 the formal oxidation state of the Ir is +4.5 and the material displays metallic conductivity. At x 0.33 the Ir is in the +5 state and the material is non-metallic. Magnetic susceptibility measurements demonstrate the materials to be spin-glasses in which short range ferromagnetic interactions are evident.
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