Sorption behaviour in a unique 3,12-connected zinc-organic framework with 2.4 nm cages

A polyhedral metal-organic framework (FJI-2) has been synthesized based on rare hexanuclear zinc clusters, which comprises 2.4 nm double-walled octahedral cages topologically featuring a new 3,12-connected structure. FJI-2 has a good H-2 uptake capacity of 149.7 cm(3) g(-1) (1.34 wt %) at 77 K and 1.0 bar, and the IAST calculation predicts highly selective adsorption of CO2 over N-2 and CH4.