期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 1, 期 31, 页码 8745-8752出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ta11517h
关键词
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资金
- National Natural Science Foundation of China (NSFC) [20971001]
- NSFC-Chinese Academy of Sciences (CAS) Joint Fund for Research Based on Large-Scale Scientific Facilities [10979014]
- Program for New Century Excellent Talents in Universities, Ministry of Education, China [NCET-08-0617]
- Anhui University
A combined ultrasound-vapour phase diffusion technique was used for the rapid synthesis of a terbium-based metal-organic framework (MOF), [Tb(1,3,5-BTC)](n). Compared with conventional solvothermal and ultrasound-assisted methods, such a kind of combined ultrasound-vapour phase diffusion technique is highly sufficient for synthesizing nanoscale MOF crystals in remarkably high yields. Significantly, the as-prepared [Tb(1,3,5-BTC)](n) nanocrystals exhibited highly selective sensing of picric acid (PA) without the interference of other nitroaromatic compounds such as nitrobenzene, 2-nitrotoluene, 4-nitrotoluene, 2,4-dinitrotoluene, and 2,6-dinitrotoluene. This makes them a potential candidate for developing novel luminescence sensors for the highly selective sensing of PA.
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