期刊
JOURNAL OF ENERGY CHEMISTRY
卷 22, 期 2, 页码 183-194出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S2095-4956(13)60024-8
关键词
carbon nanotube; graphene; edge; lithium ion battery; supercapacitor; fuel cell
资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [24310088]
- Research Center for Exotic NanoCarbon Project, Japan Regional Innovation Strategy Program by the Excellence
Nanostructured carbon materials, including carbon nanotubes, graphene and nanoporous carbon, show promise for expanding renewable energy. In particular, the configuration and electronic properties of graphene edges in relation with their electrochemical activity have become a major issue in carbon-based energy storage devices. Here, we review recent results concerning the important roles of graphene edges as the gateway for lithium ion intercalation in the anode of lithium-ion batteries, as promoters of high capacitance in carbon-based supercapacitors, and as anchoring sites for Pt nanoparticles in fuel cells. We envisage that the controlled synthesis of a specific, clean, and stable edge configuration could be achieved to maximize the electrochemical performance of nanostructured carbon-based energy storage devices.
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