期刊
ADVANCED SCIENCE
卷 2, 期 8, 页码 -出版社
WILEY
DOI: 10.1002/advs.201500071
关键词
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资金
- Natural Science Foundation of China [21373060, 21333002]
- State Key Basic Research Program of PRC [2011CB935903]
- Shanghai Pujiang Program [13PJ1400800]
- Shanghai Science and Technology Committee [08DZ2270500]
Carbon/sulfur composites are attracting extensive attention because of their improved performances for Li-S batteries. However, the achievements are generally based on the low S-content in the composites and the low S-loading on the electrode. Herein, a leaf-like graphene oxide (GO), which includes an inherent carbon nanotube midrib in the GO plane, is synthesized for preparing GO/S composites. Owing to the inherent high conductivity of carbon nanotube midribs and the abundant surface groups of GO for S-immobilization, the composite with an S-content of 60 wt% exhibits ultralong cycling stability over 1000 times with a low capacity decay of 0.033% per cycle and a high rate up to 4C. When the S-content is increased to 75 wt%, the composite still shows a perfect cycling performance over 1000 cycles. Even with the high S-loading of 2.7 mg cm(-2) on the electrode and the high S-content of 85 wt%, it still shows a promising cycling performance over 600 cycles.
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