期刊
ECS ELECTROCHEMISTRY LETTERS
卷 4, 期 1, 页码 C5-C7出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/2.0101501eel
关键词
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资金
- U.S. Department of Energy, National Nuclear Security Administration's (NNSA's) Office of Defense Nuclear Nonproliferation
- [DE-AC02-06CH11357]
To obtain Tafel constant and exchange current density data for the U/U3+ couple, a uranium working electrode was examined potentiodynamically at +/- 15 mV overpotential at five temperatures in molten LiCl/KCl eutectic salt. This pre-Tafel region was used to avoid the presence of an observed buildup of material at uranium anodes at Tafel region overpotentials. Data were analyzed using the Oldham-Mansfeld method. The Tafel constant varied inversely with temperature, due to a direct relationship between temperature and transfer coefficient. Exchange current density followed the relation i(o) = 20396e-(4143/T). This temperature-exchange current density relationship yielded an activation energy for the U/U3+ reaction of 34.4 kJ/mol. (C) 2014 The Electrochemical Society. All rights reserved.
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