期刊
ASIAN JOURNAL OF ORGANIC CHEMISTRY
卷 3, 期 9, 页码 936-939出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201402104
关键词
CH2 addends; electron mobility; fullerenes; o-quinodimethane; polymer solar cells
资金
- 100 Talents Program of the Chinese Academy of Sciences
- National Natural Science Foundation of China [21374025, 21372053, 21102028]
Three structurally analogous 54 pi fullerene acceptors, tris-o-quinodimethane-C-60 (tris-OQC), bis-o-quinodimethanemethanon[60] fullerene (bis-OQMF), and o-quinodimethane-bis-methano[60] fullerene (OQBMF), were systematically investigated. As o-quinodimethane addends on C-60 are replaced stepwise by methylene groups (CH2), the electron mobility of fullerene, the crystallinity of poly(3-hexylthiophene), and the morphology of the active layer of solar cells were simultaneously improved while bimolecular recombination in the active layer was reduced, leading to a remarkable enhancement in power conversion efficiency.
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