期刊
ADVANCES IN MATERIALS SCIENCE AND ENGINEERING
卷 2010, 期 -, 页码 -出版社
HINDAWI LTD
DOI: 10.1155/2010/360597
关键词
-
资金
- Provence-Alpes-Cote d'Azur Regional Council
- General Council of Var
- agglomeration community of Toulon Provence Mediterranean
The carbonatation of La2O3 oxide and the decarbonatation of lanthanum carbonate phase La2O2CO3 are investigated using thermal and thermogravimetry analyses under CO2 gas flow. The initial phase La2O3 is first elaborated from pyrolysis of a LaOHCO3 precursor. Then, thermal and thermogravimetry analyses are carried out under CO2 flow, as temperature increases then decreases. The carbonatation kinetics of La2O3 is determined at three fixed temperatures. Electrical impedance spectroscopy is performed to determine the electrical responses associated with ionic mobilities and phase changes, in the temperature range 25 to 900 degrees C. The electrical conduction during heating under CO2 gas flow should be linked to two regimes of ionic conduction of the carbonate ions. From these electrical measurements, the ionic mobility of carbonate ions CO32- is found to be close to 0.003.10(-4) cm(2) s(-1) V-1 at 750 degrees C for the monoclinic La2O2CO3 phase.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据