4.6 Article

Cyclic Carbonates as Green Alternative Solvents for the Heck Reaction

期刊

ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 2, 期 7, 页码 1739-1742

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AMER CHEMICAL SOC
DOI: 10.1021/sc5002287

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Green solvents; Kamlet-Taft; REACH; Palladium; Dipolar aprotic solvents

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Organic cyclic carbonates (ethylene and propylene carbonate) are shown to be viable greener solvents for use in Heck reactions, offering a highly effective alternative to traditionally used dipolar aprotic solvents such as NMP, DMF, and DMAc.

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