4.6 Article

Nanoporous Titania-Supported Gold Nanoparticle-Catalyzed Green Synthesis of 1,2,3-Triazoles in Aqueous Medium

期刊

ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 1, 期 11, 页码 1405-1411

出版社

AMER CHEMICAL SOC
DOI: 10.1021/sc400147r

关键词

Gold nanoparticles; Cycloaddition; Huisgen reaction; Heterogeneous catalysis; Triazole

资金

  1. UGC, New Delhi
  2. CSIR, New Delhi

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Nanoporous titania-supported gold nanoparprecipitation method, and the synthesized nanoparticles have been characterized by XRD, SEM, HRTEM, EDAX, BET adsorption isotherm, and IR and UV vis spectral techniques. The efficiency of this catalyst toward green organic synthesis has been studied by carrying out the 1,3-dipolar cycloaddition of organic azides with a variety of terminal alkynes in water. The reaction proceeds regioselectively yielding the corresponding 1,4-disubstituted-1,2,3-triazole derivative in good to excellent yield.

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