期刊
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
卷 11, 期 -, 页码 2795-2804出版社
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.11.300
关键词
chromane derivatives; metathesis catalyst; nitrogen heterocycles; olefin metathesis; Ru-carbene
资金
- Polish National Science Centre [UMO-2011/02/A/ST5/00459]
- EU, Operational Program Development of Eastern Poland [POPW.01.03.00-20-034/09-00]
The synthesis of a new type of Hoveyda-Grubbs 2nd generation catalyst bearing a modified N-heterocyclic carbene ligands is reported. The new catalyst contains an NHC ligand symmetrically substituted with chromanyl moieties. The complex was tested in model CM and RCM reactions. It showed very high activity in CM reactions with electron-deficient alpha,beta-unsaturated compounds even at 0 degrees C. It was also examined in more demanding systems such as conjugated dienes and polyenes. The catalyst is stable, storable and easy to purify.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据