期刊
ENERGY TECHNOLOGY
卷 3, 期 6, 页码 625-631出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ente.201402213
关键词
supercapacitors; electrolytes; energy storage; metal oxides; thin films
资金
- DAE-BRNS, BARC Mumbai, India [2012/34/67/BRNS/2911]
- Department of Science and Technology (DST) through PURSE
- FIST & University Grant Commission (UGC) India through DSA-I scheme
The growing interest in portable and consumable electronics demands efficient and low-cost energy storage devices with excellent flexibility and of light weight. We demonstrate flexible high-performance all-solid-state thin-film asymmetric supercapacitors (ASSTF-ASCs) using -MnO2 and -Fe2O3 thin films as positive and negative electrodes, respectively. The as-fabricated ASSTF-ASC devices have excellent electrochemical performance with extended potential window of 2.0V and excellent cycling stability for 2500 cycles. Impressively, an MnO2//Fe2O3 asymmetric cell demonstrates high specific capacitance of 145Fg(-1) with a high energy density of 41Whkg(-1) while maintaining a power density of 2.1kWkg(-1). A parallel combination of two MnO2//Fe2O3 asymmetric cells is able to illuminate a panel of 31 light emitting diodes (LEDs). These findings may offer new opportunities for the use of asymmetric configurations in energy storage devices for various portable electronic systems.
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