期刊
ACS MACRO LETTERS
卷 1, 期 7, 页码 845-847出版社
AMER CHEMICAL SOC
DOI: 10.1021/mz3001397
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资金
- NSF [GOALI CHE-0957386]
- DOE [DE-FG-02-10ER16198]
- NRF of the Korean Ministry of Education, Science and Technology [NRF-2010-C00059]
- Marcus and Amalia Wallenberg Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0957386] Funding Source: National Science Foundation
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1001903] Funding Source: National Science Foundation
A facile one-step synthesis of functionalized valerolactones was carried out by the conjugate addition of thiols to the alpha,beta-unsaturated valerolactone 5,6-dihydro-2H-pyran-2-one. The resultant 3-mercaptovalerolactones undergo ring-opening polymerization in solution or in the melt to generate polyesters functionalized either with benzyl mercaptans or oligoethylene glycol pendant groups. The copolymerization of the 3-mercaptovalerolactones with epsilon-caprolactone generates random copolymers.
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