期刊
CHEMELECTROCHEM
卷 2, 期 10, 页码 1576-1581出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.201500119
关键词
electrochemistry; lithiation; nanoparticles; transmission X-ray microscopy; X-ray absorption spectroscopy
资金
- National Science Foundation (NSF) Graduate Research Fellowship [DGE-114747]
- Stanford Precourt Institute of Energy
- Department of Energy, Laboratory Directed Research and Development [DE-AC02-76SF00515]
State-of-charge maps of a LiFePO4 electrode in standard nonaqueous electrolyte are recorded inoperando with a resolution of tens of nanometers by using hard X-ray spectroscopic microscopy. We observe spatially inhomogeneous charging and discharging of the composite electrode, with predominately Li-rich and Li-poor micron-scale agglomerates. There appears to be no correlation between the agglomerate size and the (de)lithiation pathway. Additionally, we observe that the electrochemical heterogeneity exhibits a last to delithiate, first to lithiate behavior, in which the regions that are the last to charge are also the regions that are the first to discharge. These observations suggest that the nanoscale pore structure within the agglomerates dominates lithium-ion transport.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据